Is there a physical reason behind the lower distortion? Is the glass different? Does the distance from the front and rear elements make a difference between RF and SLR? What causes the images to have low distortion?
Inherently, wide-angle lenses for RF cameras have their rear lenses fairly close to the film plane.
Imagine the film image window, and some hypothetical lines that describe the outermost light rays to the edges of the film window. The angle between these lines is defined by the lenses viewing angle. By design, these lines need to intersect in the lenses optical center. The shorter the focal length of the lens (the wider the viewing angle), the closer the intersection of these lines will move to the film plane, which explains why the rear lens will extend particularly close to the film plane.
SLRs need to have a minimum distance between the lenses rear element and the film to provide for the motion of the viewfinder mirror. This distance is a serious design problem for SLR wideangle lenses, as inherently these would need to extend much further into the camera body than is permitted for a meaningful VF mirror motion.
On order to provide space for this mirror, wideangle lenses for SLR cameras need to use a specific design that moves the entire lens assembly further away from the film plane, effectively featuring different viewing angles for the front and back (film) sides of the lens.
In order to achieve this goal, SLR wideangle lenses use a so-called retrofocus design, which includes a fairly large number of additional lenses over the equivalent RF camera lens.
These lenses are what introduces the additional distortion in SLR objectives.
You can see this conceptual diffference between RF cameras like the M-bayonet Leica and any SLR in the distance between lens bayonet flange and film plane. Virtually all full-format and APS-C format SLRs feature a film-to-flange distance that is almost double that of the Leica M bayonet flange to film distance.
As a consequence, it is hardly possible to adapt any RF lens to an SLR camera without permanently moving the VF mrror out of the way - effectively disabling the SLR's viewfinder and its associated functions such as autofocus and exposure measurement.