There are three airports in London (and at least two more which claim to be connected to London but really aren't). Being based near London, I've flown from them all (and with film). I've had hand-checks every single time. Heathrow is definitely the worst of the three (especially Terminal 5, the newest one); Gatwick and London City are much more accommodating. But in general, if you're not an ass, they'll hand scan for you.
It helps if you have at least one film over 400 ISO with you - or if you mark up a roll of 400 as "push to 1600", but you might have to explain what that means!