In LR4 I hit Auto WB and got a pretty good result but still a bit too blue. The t-shirt is white in the light and pale blue in the shadows. Temp= +50, Tint= +14.
Next I grabbed the Temp slider and increased it to +85. This gives nice warm skin tones while the t-shirt is a warm-white. Looking good.
Added Vibrance +25 and Saturation +11 to give a stronger colour to his face. Boosted Clarity to +15, and then pulled back the Highlights to -19 as they were looking a little pale after boosting Clarity.
Vignetting -35.
The only remaining problem is the blown t-shirt. I'd use an adjustment brush to bring it back within the exposure range (Edit: just done. Also desaturated the white t-shirt at the same time. But forgot to do the same for the neck strap
🙁).
Pulled back exposure to -0.10 for a more conservative look.
That now looks pretty good to me. What do you think?