Delta 3200 Rodinal/Xtol Stand

bwcolor

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I gave the above a try and rated my exposures @EI 1200. Below you will find a cropped 6x7 image 200ml Xtol, 5ml Rodinal, 1/4 teaspoon Borax, 2 Teaspoons Ascorbic Acid to make 1000ml. 68 degrees for 90 minutes. 15 seconds of slow inversions for first five minutes and then stand. Seems like I have less grain than straight Rodinal. I think that I should have rated this film more like EI 800. I'm not particularly happy with the shadows. I've seen better TMY2 @ 640. The speed allowed me to shoot in questionable light with my Mamiya 7ii. Images were from a family Christmas party...nothing artistic, but should anyone be interested in the combination..here it is:

4205457206_d641e073f3.jpg
 
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I just recently developed a couple of rolls of ISO 100 film in 120 and it looks like the Ascorbic Acid neutralized the dilute Rodinal and all that I ended up with was perfectly clear film. So, why doesn't it do the same thing here, or does it and what I'm looking at is simply the Xtol developer? I don't particularly like the results above, but I am curious.
 
There are two a good reasons why Ilford recommends against Rodinal with Delta 3200: low speed and huge grain.

I don't wish to appear rude, but are you trying to run before you can walk? In another post you appeared not to know the difference between ascorbate and ascorbic acid (= the salt of an acid and the acid itself). Do you know the theory of how buffered developers work?

Now you're using stand development with a fast film: decreased agitation = less toe speed at a given contrast. What is the basis for your unusual combinations of developer, agitation, etc? Have you read the leading books on photo chemistry such as Glafkides or Haist?

You may know more than I; but equally, I can't help feeling that you may also be falling for fads.

Cheers,

R.
 
You are right, except that I'm not so sure that I can walk either.

I understand that "stand" development with Rodinal alone is counter-productive with fast films. I also know that adding Rodinal increases grain and apparent sharpness/acutance compared to other developers such as Xtol. I haven't read a single book on developers and my only chemistry was undergraduate school many years ago. What I do have is more money than time and poor results are my method of learning. I have fallen for Google search and the recommendations of others and then I try to piece things together after the fact. I was aware of the shortcomings of this combination prior to pouring the developer, but my source, as sited elsewhere, didn't seem to make the distinction between ascorbate and ascorbic acid and I haven't a clue as to how each class of developers work.

Your suggestion of reading a book prior to experimenting is certainly valid and would have been my only choice prior to the Internet.

I'll take your slap-down as good direction to turn in that you have spent a very long time educating folks on these very same subjects.

If you would be so kind as to suggest a current book of moderate cost addressing these topics, I would be interested in ordering it. Amazon didn't have anything in print by Glafkides and used works by Haist were close to $200. My comments regarding more money than time don't extend to two-hundred dollar books.... thanks again .. Gary
 
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My thoughts are:

Rodinal and Xtol mixed is a good combo for many films, but D3200 would not be my choice. With that film I go for Xtol 1+2 (purely because this is my std dilution with other films) or DDX. You do get a balance of developer characteristics; however, this is mort apparent and useful with films thyat would otherwise be too smooth with Xtol alone for your pictorial needs (like Delta 100 when shooting something you want to have evident bite and edge)

I find that reduced agitation allows for better highlight control or, if you develop longer, a slight bump in speed.

Roger, you said reduced agitation gives less toe speed for a given contrast index. Is it not the opposite?

Still, overall, I would not bother with such complex mixtures. I find that simply adding rodinal to my Xtol brew either on a 1:100 or 1:200 basis allows for subtle changes in grain and bite with predictable results. I like the results particularly with D100, FP4+, Neopan 400 and Foma 100/200. TriX is not bad either if you want grain, but less than rodinal alone of course.
 
I tried it because I wanted to see how the two worked together. I realized prior to pouring the developer combo that this wasn't a great combination. I only posted because I had mentioned in another post that I would do so. I have two rolls of Delta 3200 in 120 to develop and I plan on using Xtol.

I picked up on a thread regarding Neo 1600 and Rodinal. Again, a combination that I would not expect to work well, but the member swore that it did. I shot four rolls at EI 640 and am scanning as I post. This time, it looks like I'm going to be rather happy with the results. I have limited myself initially to two developers and a range of film. My color film preferences were much easier to sort out.

GB Hill: I saw the same book on Amazon when searching for the authors previously suggested. I'll wait a few days to see if there are any other suggestions and then order books. I would like to have some idea what I'm doing. thanks..

Here is the Neopan 1600 @ EI:640 in Rodinal..Christmas morning:
4215388904_65399051a1_b.jpg
 
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bwcolor, depends on what you want, but rodinal with Neopan 1600 or D3200 is going to give you less speed and more grain than Xtol or DDX (or D76 even). Neopan 1600 at 500-800 can give lovely results in Xtol 1+something and is good in DDX. You'll (IMHO) get superior tonality, especially for children, with better mid tone separation. D3200 in Xtol 1+something is IMHO as good as it gets at this speed. I love the tones and crisp grain. These fast films dont need an acutance develooper, just something that does not dissolve the grain if you wish for a crisp result. if you do use an acutance developer, IMO, you just get gravelly tones and no benefit. Xtol 1+2 gives a good 2/3 stop more speed than rodinal too.
 
You are right, except that I'm not so sure that I can walk either.

I understand that "stand" development with Rodinal alone is counter-productive with fast films. I also know that adding Rodinal increases grain and apparent sharpness/acutance compared to other developers such as Xtol. I haven't read a single book on developers and my only chemistry was undergraduate school many years ago. What I do have is more money than time and poor results are my method of learning. I have fallen for Google search and the recommendations of others and then I try to piece things together after the fact. I was aware of the shortcomings of this combination prior to pouring the developer, but my source, as sited elsewhere, didn't seem to make the distinction between ascorbate and ascorbic acid and I haven't a clue as to how each class of developers work.

Your suggestion of reading a book prior to experimenting is certainly valid and would have been my only choice prior to the Internet.

I'll take your slap-down as good direction to turn in that you have spent a very long time educating folks on these very same subjects.

If you would be so kind as to suggest a current book of moderate cost addressing these topics, I would be interested in ordering it. Amazon didn't have anything in print by Glafkides and used works by Haist were close to $200. My comments regarding more money than time don't extend to two-hundred dollar books.... thanks again .. Gary

Dear Gary,

I am very glad that you did not take my 'slap down' (as you put it) the wrong way. I thought for some time before making the point.

Try an inter-library loan on Glafkides or Haist. Alternatively look for L.P. Clerc, or Jack Coote's Ilford Monochrome Practice, or Sheppard & Mees, The Photographic Process, or Neblette, Photography, Its Principles and Practice or John & Field, Textbook of Photographic Chemistry. None is recent: the technology is pretty mature.

They're all (with the possible exception of Coote) pretty chewy but they'll revive your undergraduate chemistry and demonstrate that a lot of the so-called modern technical books on developer formulation are, shall we say, empirical at best.

Also, a lot of people see what they want to see: neg/pos B+W photography is an extraordinarily flexible process and you can get away with all kinds of things that are theoretically undesirable, such as pre-washes/pre-soaks.

It's worth knowing too that even the Great Names don't agree. I have had the privilege of meeting some of them, and while Grant Haist has his doubts about using more than a single developing agent, Geoffrey Crawley cheerfully uses three.

The reason I've never tried to do a book on this is that (a) it's bloody difficult to do properly and (b) I don't want to assemble a populist but fundamentally ill-informed (and sometimes ill-copied) collection of formulae: it's difficut to copy-type formulae accurately. For that matter (c) no-one would read it: there's an awful lot of "My mind is made up. Do not confuse me with the facts."

@ Turtle. I know I have a talent for writing the exact opposite of what I mean to say, and having to correct myself afterwards, but no, on this occasion, on re-reading it, I find I was the right way around: more agitation = more toe speed for ISO standard contrast. Note 'ISO standard contrast', however. Compensating effects are another can of worms entirely -- and again, sometimes owe as much to what people want to see as to what is sensitometrically there.

Cheers,

R.
 
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I haven't much Xtol left, so I'll save it for the 3200, for now. Next batch of 1600 will be Xtol. I intentionally scanned at 4000 on my 9000ED. I've read up on scanners and know the downside and may not be best choice and 9000ED might not even do 4000. Anyway, when viewed at the pixel level, the grain is extremely fine. This was what was claimed and in fact this is what I got. Regarding the tonality, I can't make any claims there, but the fine grain was a surprise. This and all the photos were taken in very low contrast with my fastest shutter speed at 1/30 sec. I'll need to do some work in PS. This one is pretty much out of the scanner and sharpened.

I completely forgot about the library. Haven't been for years and we have a new, three month old library, a few minutes away.

Thx
 
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I just recently developed a couple of rolls of ISO 100 film in 120 and it looks like the Ascorbic Acid neutralized the dilute Rodinal and all that I ended up with was perfectly clear film. So, why doesn't it do the same thing here, or does it and what I'm looking at is simply the Xtol developer? I don't particularly like the results above, but I am curious.

There are two reasons why this may have worked. Xtol has large buffering capacity which Rodinal does not have. Xtol's "weakly alkaline" (their terminology from the patent, not mine) accelerator is a buffer, probably of metaborate-boric acid. Buffers resist pH change when more alkaline or acidic material is added to them. It's also possible that the Rodinal you added and the ascorbic acid effectively cancelled each other out. Stick with sodium ascorbate if you're going to add it to existing developers.

Marty
 
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