JoeV
Thin Air, Bright Sun
Here's a question for the more knowledgeable: does this method of shooting contain a wider range of tones in the data than B&W film? I've seen some really dramatic images 'created' this way.
I don't presume to be "more knowledgeable", but here goes. The spectral sensitivity of B/W film varies between specific brands and types, but it theoretically could contain all the tonal information of your original color scene, but expressed as a gray scale rather than as color information.
The place where using channel mixer is very powerful is being able to alter the spectral sensitivity of the original color image, to achieve whatever B/W effect is required. Of course, the digital camera's sensor also has a limited spectral response, as does film, so using channel mixer is really like using a continuously variable color filter over the lens, but after the fact, rather than in front of the lens. BTW, you can also use color filters on the digital camera's lens to achieve a similar effect.
To respond to the OP's question, the color spectrum chart is a diagram of wavelength (i.e. color) versus intensity (we see this type of chart when discussing the spectral response of film, for instance), whereas monochrome images map light intensity over a band of wavelengths that have been normalized to a range of gray tones.
So various shades of gray aren't mapped to specific colors; rather, objects in the image field are mapped to various shades of gray by the spectral senstivity of the sensor or film. And this isn't a unique mapping, where a particular shade of gray equates to a specific wavelength; rather, you could have the case where various colors in the image field all map to the same shade of gray, like light green and dark green as an example. It all depends on the specific sensitivity of the media being used.
Theoretically you could have a B/W medium that has a linear response across a continuous band of wavelengths; in that case your original supposition would be correct; but I know of no real-world sensor system with those properties.
~Joe
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