In my experiance, both are about equally reliable. But then, so is the old Kodak ball bearing shutter on a B&L Rapid Recitilinear I've got from the 00's (1900's that is 🙂 ). The big thing is to get any old shutter you intend to use regularly serviced so that you can get it to the point where the speeds are consistant and you know what they are. The Syncro-Compur on my 135/5.6 Symmar was CLA'd by Carol Miller and has tested speeds of: 1, 1/2, 1/5, 1/10, 1/25, 1/50, 1/100, 1/200, 1/400. Yes, 1/400 not the 1/500 marked & IME that's doing pretty good.
Wiliam