The salient parts of the German writeup on Rodinal
The salient parts of the German writeup on Rodinal
Hi,
I'll try and render the salient parts of the writeup.
http://home.arcor.de/piu58/fotoweb/aufsaetze/Rodinal.pdf
I am skipping the Intro, where general well known and undisputed qualities of Rodinal are mentioned.
- At the beginning of the writer's experiments with Rodinal and temperatures below 20 deg. Celsius were rumors on the Internet.
- Already at 18 dec. Celsius clearly visible differences (compared to dev. @ 20 deg.) emerge, and even stronger @ 16 deg. Celsius. The development of the deeper layers of the emulsion are enhanced, resulting in an effective speed enhancement of about half a stop. This way box speed may be attained.
- A stronger dilution (1:100) may lead to similar results, but the negative will turn out less contrasty (duller) overall. Also, one may run into problems with exhaustion of the developer.
- For every degree Celsius below 20 deg. increase development time by a factor of 1.13. The factor for a reduction of 2 deg. is thus 1.3, and 1.6 for a reduction of 4 degrees. Of course this means that long(er) development times may be inconvenient. The author does not take any measure to prevent the tank from heating up during development.
According to the author this development procedure results in a nice balance of sharpness and graininess. While less graininess is possible with other methods or developers, these will also reduce sharpness. Also, other developers may certainly yield yet another half stop of speed.
- For contrast control with Rodinal the author recommends increasing the strength of the dilution instead of prolonging development time, since this may not lead to the desired effect of increasing contrast, due to exhaustion of the developer.
- Attempt at a theoretical framework: the lower temperatures reduce activity of the developer. The resulting longer developer times increase the chance of developing/reaching the lower/deeper layers of the emulsion. While a higher dilution of the developer may in principle do the same thing, the author has no explanation why the "cold method" gives "better" results.
Fine-grain-developers like A49 or Ultrafin+ are tuned to development of the above mentioned deeper levels of the emulsion from the get go. "Cold" Rodinal achieves the same thing, however without producing mushy grain, as opposed to these fine-grain-developers.
---------------------------------------------
Hope this helps. My take on it is that there may very well be something to this. If you use the search function on photo.net there is some info on cold development, too. I can not comment on the whole "deeper layers of the emulsion" aspect, and whether the change in film design over the last decades may or may not come into play here.
Greetings, Hannes