If the second curtain is slower than the first curtain, BUT the speeds appear to be ok, that's ok, it is how it is supposed to be. The idea is to have a "clash" first curtain and "swoosh" second curtain. In my Zorki the same happens, I have a slow second curtain and a quite quick first curtain. The shutter speeds are very good compared with my Yashica reflex and my old man's Canon A1.
Now, if you see a noticeable difference compared with other cameras when you enter the slow speeds, the yoy may want to adjust the tension of the barrels. This is not easy, but it can be done with not too much effort.
Remember that in the Zorki 4, the first Slow Speed is 1/60, and the last fast speed is 1/30. This sounds strange, but the slow speed mechanism engages in 1/60 and then jumps to 1/15. As Rick Oleson explains, it seem that there were not too much space to put the 1/30 between 1/60 and 1/50, that's why 1/30 is in the opposite side.
Check if the shutter speeds are fine... if they are fine, don't touch the camera I'd say. To reach the needed gears you need to do a more complex disassemble of the camera... you need to take out the lens mount, the whole front cover, the piece that holds the lens mount and the light baffles, and the light baffles. If you do, remember to take a note if the disassemble procedure and where each screw goes.
Another solution is to put some lighter fluid in a small syringe, and put a small drop on the curtain guides. I did not do that since lighter fluid is very aggressive and these cameras are almost 40 years old... mine at least, and i'ts a younger one here 😉
As I said... if the shutter speeds are fine, leave the camera like it is, because it is supposed to be a fast first curtain and a slow second curtain.
I hope this helps!
Cheers
Bas.