I'm sure everyone has made that mistake at some point, hopefully not often !
If you always cut a shaped leader, or use commercially loaded film, then simply ripping off the shaped part of the leader will indicate that it is used. If there is any exposure info (push/pull, flat light, contrasty etc etc) then you can write a small note on the tongue of film sticking out of the cassette.
For a quicker reload, by avoiding going through the five used rolls before getting to the unused one, it is also a good idea to keep the rolls/cassettes separately anyway, but the more chances one gets to correctly identify which roll is which, the better....