Ansel Adam's book "The Camera" has a very informative discussion about the characteristics of focal plane versus lens shutters and their actual efficiency, strengths and weaknesses in use. Chapter 6 has a paragraph entitled "Shutter Efficiency" and he suggests that usually lens shutter speeds are calculated on basis of full aperture. It also discusses changes in effective speed at other apertures; in general leaf shutter efficiency decreases at higher speeds as it deviates from theoretical ideals more than at slower speeds.
I acquired a factory service manual for dozens of different Compur shutter ex ebay a few years ago which provides detailed information about adjustment and lubrication etc. They were built to tight tolerances so a fairly notorious for running slower than their stated maximum speeds and Deckel themselves stated a generous 20% acceptable tolerance for accuracy. As long as the shutter adjustment is correct and the mainspring and booster spring (if applicable) is in good condition I am not sure how much more accurate you are likely to make one that is clean, lubricated and in good working order. Please let us know how you fare though, as it would be interesting to hear some real-world experience of investigations into this.
Regards,
Brett