I was looking at the "Definitive Collection" myself tonight. Of course he is so well known as the quintessential war photographer, but there are so many non-war shots that are quite amazing. Just to mention a few:
the cello player, photo #393 on page 243
tour de france photo, #420 on page 262
hemingway, sun valley, #459 page 287
himself and steinbeck, #777 page 463
one more I have to mention
picasso, gilot, and picasso's nephew, #798 page 479
unbelievable stuff.