The Hi-Matic 7S used a PX625 (mercury) battery. You can't get those anymore. Most of the drop-in replacement batteries in 625 size have the wrong voltage (1.5 volts instead of 1.35 volts) and will give you inaccurate exposures. The one exception is the Wein cell, which starts off at 1.4 volts, then very quickly drops to 1.35 volts and stays there. However, they are not cheap. Here's my solution, that I reached after years of doing this:
1. Buy a 625A (alkaline) battery and tape a wire to both ends so it discharges for 24 hours.
2. Look closely at the battery. You will notice that a replacement 625A battery is actually a smaller battery that has been force-fit into a metal shell. These can be 675 batteries or 386 batteries. It is that 625-sized shell that you want to save and you want the kind that uses a 675 battery in the center.
3. Remove the battery from the shell. Wear eye protection and rubber gloves, because the stuff inside an alkaline cell is corrosive and you will probably have to take it out in pieces.
4. Once you have it out, drill a 1/8 inch hole in the bottom of the shell. This hole will allow air to get to the battery you are going to put in there and will be used to poke the fresh battery out of the shell when it is used up.
5. You can use the shell as an adapter for #675 hearing aid batteries, which are the right voltage and only cost about $1 each. Buy some of those, stick one in it and put it in the camera.
Edit: Of several methods for powering the camera with the right voltage, that's the cheapest I know of that is elegant, will work right and won't require modifying the camera.