Thanks. Yeah I have only had the camera a couple of days and not had a chance to do many 'real' shots with it (I came across this phenomena on a wet evening testing AF), so I'm guessing this is an unusual useage situation - one I'm hopefully not likely to encounter in my actual photography. The photos I took yesterday at sunset on the downs are gorgeous.
Not sure I follow what you suggest about over exposure? Even if it were, why would it cause purple fringing? When I stopped down, the camera was still setting shutter speed, so the overall exposure was the same in the highlights, I double checked this in camera raw.
I received my 23mm and it does exactly the same in that example, so I think it's just the lenses, unless you mean there's some weird sensor 'bloom' which is causing it? TBH I'm not that concerned now I know it's not a fault with that particular lens, but it's odd the in camera processing doesn't take care of it...
Once I get my adapter, I'll try with my Zeiss 50 1.4, which I know is relatively immune to CA.