Very different in use. 35 is natural, whereas 28 is the first FL to really introduce 'dynamism.' 24 more so and 21 and beyond are 'extreme' in the perspective distortion and shaping of spatial relationships.
You can go out with a 35 and be screaming for a 28. I was today. Still, I made the 35 work. I opted out of regular use of my 28 for a 24, but I did not have it with me.
28 allows you to get close and make a subject prominent in the frame, while including quite large objects further back (as they are shrunk in size). with 35 you can't do that nearly so well, but you can gain a bit more 'stand off' distance.
I decided a 24mm lens on a 0.58 body was a better compliment to my anchor FL, which is 35mm (on a 0.72) but were I not to have the 24 I would certainly bother to carry a 28 with me, because there is quite a difference in use between 28 and 35 IMHO.