isn't Velvia slide film? Why wouldn't you use print film if a print is the desired product?
Is the enlargement going to be made from a scan of the slide, or using inter-negatives, or some other process? Is the digital image file printed on a consumer grade inkjet or professional equipment?
If this is only theoretical, why not compare with another film, something slower, perhaps? Why Velvia 100, specifically? Is the judgement for "best" going to involve the use of a loupe, or standing back ten feet and looking at color accuracy, smoothness of tones, or aesthetic impressions only? Is there a reason you can't do both, then ask passersby their opinion?