What I would really love to learn, when reading this kind of discussions, is the hydraulic and chemical detail of the development process.
The same goes for concentration and agitation of the developer. Higher concentrate will bring more developer into the emulsion to react with the silver halides. And agitation will allow for quicker refresh of the developer that's in the emulsion.
And then on a smaller level, what's the role of grain? What is a grain actually? A clob of silver halides? Is it the grain itself that is activated by exposure? Is a grain something binary: activated yes/no - developed yes/no, or is it capable of storing gradations? And about sharpness: Some developers retain the structure of the grain (e.g. Rodinal), others seem to break it down or soften it.
Can someone recommend a good book that covers this process??
Groeten,
Vic
Long ago, many of us were doing probably too many experiments, but I had a friend with a densitometer and a very good exposure meter. He spent a year photographing gray cards, checking to be sure they were evenly illuminated, and trying various agitation methods, checking the negatives with the densitometer for even development.
We all knew that the common agitation of the day, often turning the film using a spindle, produced more velocity at the outside, and just inverting the tank would possibly lead to uneven hydraulics, so the best compromise seemed to be shaking the tank up and down, except I pointed out that the middle of the frame would get more fluid flow.
Bob finally started shooting sheet film and developing it with a paint brush, painting the developer from one end to the next for the most even development, which for him seemed to yield a very even gray, verified by his testing. Then I pointed out that the leading edge- well you get the picture. At the end of the year he had used a lot of chemistry and film.
I did and do prerinse in most cases, but I also try to use developers that allow reasonable length development. And I use tanks that allow rapid filling from a beaker, and rapid emptying of used developer, plus a generous amount of developer.
I do not rap the tank sharply, any bubbles that firmly attached are not of this earth, and it can cause the tank to crack along the injection molding lines. I have seen people slam a stainless tank down hard enough to crack walnuts. I think some gentle tap is OK. I normally agitate at normal recommended intervals, but seem to find different intervals recommended for the same developers in different sources.
I also use plain tempered water for rinse, rapid fix with hardnerer, a good wash in tempered water, and a final rinse in distilled.
Probably reasonably good treatment, certainly better than machine handling.
Bob did get a letter from AA, saying he had great technical skills, possibly the best he had seen, but knew nothing about photography. He framed it.
Regards, John